Re: [EVGRAY] Re: Zeolite

Database ID: 105133
2017-12-13T20:47:46+00:00
Warren Keillor <[email protected]>

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Norm-14 C today, and staying that way.Zeolite you say?I wonder what a 12'x 36' silo full of the stuff might do, as a heat storage container?I am pouring concrete floors with plastic tubing arays inside, in all the barns.We are still dickering around with the thermal panels to build.Cheers Warren

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  On Wed, Dec 13, 2017 at 12:43 PM, Norman Wootan [email protected] [EVGRAY]<[email protected]> wrote:       
 

Started researching "Zeolite" as a thermal energy storage 'sink" back in 1979 after learning that it has capability to store 13X more energy than any other method.  I ordered a pallet 300kg "Natural Zeolite"  from Japan since it is volcanic source and is used by garden farmers there.  I also bought a drum (55 gal) of 10X molecular save synthetic zeolite from Union Carbide, Mobile, AL. Built a solar collector/heat storage apparatus with highly  successful results. Zeolite  works by the absorption/ de-sorption principle!  Norm
 
 
 On 12/13/2017 1:49 AM, mirco Sangalli [email protected] [EVGRAY] wrote:
  
     Accumulatori termici per ottimizzare la distribuzione nei momenti di picco degli impianti di teleriscaldamento. LA ZEOLITE.
 ( un mc di metano = 10,5 kWh termici = 380 Mj = 9120 Kcal) Il calore che si accumula nel processo di adsorbimento del vapore acqueo nei materiali adsorbenti, tipo zeoliti, silica gel o certi tipi di argille, tutti usati diffusamente come disseccanti, è pari alla somma del calore latente di evaporazione/condensazione dell'acqua + un'energia di legame che varia secondo il materiale adsorbente. Come molti sapranno l'evaporazione/condensazione dell'acqua è tra i processi fisici più energetici in natura, basti pensare che l'energia che occorre per far evaporare un litro d'acqua è tra 5 e 6 volte quella necessaria per innalzarne la temperatura di 100 gradi. Nell'adsorbimento l'energia in gioco è ancora più alta per via del forte legame tra le molecole d'acqua e il materiale adsorbente. Ad esempio per le zeoliti di tipo 13X, per ogni mole di acqua, o meglio di vapore d'acqua (18 g) che viene adsorbita, si libera un calore pari a 15 Kcal (62 KJ, ovvero 17,2 Wh).
 In altre parole, per ogni litro d'acqua (o forse sarebbe meglio dire per ogni kg di vapore acqueo) adsorbito/desorbito l'energia coinvolta 10 KWh.
 Dato che la percentuale d'acqua che può essere adsorbita nei pori della zeolite arriva anche al 30% del peso della zeolite, facendo un po' di conti si arriva a cifre di tutto rispetto, fino a 188 KWh/m3, vale a dire che in un serbatoio di 100 litri di zeolite si potrebbero accumulare A TEMPERATURA AMBIENTE e senza dispersioni, quindi a tempo indeterminato, quasi 19 KWh, ovvero quanto in un serbatoio d'acqua calda di 300 litri che oltre a essere molto più ingombrante è soggetto, tra l'altro, a inevitabili dispersioni, per quanto ben coibentato (e la coibentazione aumenta l'ingombro).
 Certamente non è tutto così semplice, all'interno del materiale bisogna lasciare degli spazi vuoti per far circolare l'aria calda o l'aria umida a seconda che si voglia accumulare o recuperare calore, ma la cosa più interessante è proprio la possibilità di conservare  senza dispersioni un "calore potenziale" a temperatura ambiente.
  Forse fra una decina d'anni gli attuali sistemi pannelli-serbatoio acqua di accumulo acqua-acqua saranno soppiantati da sistemi ad aria-zeolite,.
    
 
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